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  • Plate XIV · section 05 of 13

    Salts, and the hydrate trap

    White flakes of calcium chloride in a glass Petri dish
    Twenty-five grams of calcium chloride in a Petri dish: depending on whether the salt is anhydrous or hydrated, the same weighing does not bring the same calciumRoi.Frvr · CC0

    The minerals historically used are calcium chloride, magnesium sulfate, magnesium chloride, sodium bicarbonate and potassium bicarbonate; calcium carbonate, calcium sulfate and calcium citrate exist but are harder to find or to dissolve, the citrate acting on alkalinity through an anion different from bicarbonate. Food-grade minerals are required: laboratory grades, which are purer, may contain impurities unfit for consumption, heavy metals included.

    And the hydrated form must be read on the label: a hydrate carries a fixed number of water molecules that weigh on the scale. Weighing calcium chloride believing it to be anhydrous when it is tetrahydrate seriously underestimates the calcium added. Calcium chloride is sold mostly anhydrous, as small white spheres; magnesium sulfate mostly heptahydrate, which is Epsom salt, transparent crystals like snow; magnesium chloride mostly hexahydrate, large milky flakes; the bicarbonates have no hydrate.

    Three properties to set, alkalinity, hardness, magnesium-to-calcium ratio, and five ingredients: there are several combinations for the same water. The choice between magnesium sulfate and magnesium chloride is historical, it is not known whether the anion changes the taste; the choice between sodium and potassium bicarbonate may matter a little, since sodium can mark the profile slightly, far less than magnesium and calcium.

    Gagné 2021, pp. 26-29
    SaltCommon formWhat it provides
    Calcium chlorideCaCl₂ anhydrous, white spherescalcium, chloride
    Magnesium sulfateMgSO₄·7H₂O, Epsom saltmagnesium, sulfate
    Magnesium chlorideMgCl₂·6H₂O, milky flakesmagnesium, chloride
    Sodium bicarbonateNaHCO₃, no hydratealkalinity, sodium
    Potassium bicarbonateKHCO₃, no hydratealkalinity, potassium
    Calcium carbonateCaCO₃calcium and alkalinity, very poorly soluble in pure water
    Gagné 2021, pp. 26-28
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